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So in this final part of the lecture 
we'll solve the Cooper problem, which is 

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00:00:05,206 --> 00:00:11,274
a problem of weakly attractive electrons 
near the thermos surface that form pairs, 

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00:00:11,274 --> 00:00:17,810
so-called Cooper pairs bound states of 2 
electrons. 

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And as we discussed these Cooper pairs, 
the, at low temperatures, they both 

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00:00:22,226 --> 00:00:26,386
condense into [INAUDIBLE] condensate 
should become superfluid, and this is 

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00:00:26,386 --> 00:00:31,364
this amazing state that we know as 
superconductor. 

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00:00:31,364 --> 00:00:34,724
I should mention that we will see 
actually the solution to the Cooper 

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00:00:34,724 --> 00:00:38,924
problem will involve essentially the same 
method we used in the first lecture this 

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00:00:38,924 --> 00:00:42,452
week in the context of single particles 
quantum mechanics, so it's going to be 

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00:00:42,452 --> 00:00:47,904
actually very simple. 
Technically, a very simple solution for a 

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00:00:47,904 --> 00:00:51,406
Nobel prize winning work anyway. 
So, it's not trivial but, you know, this 

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00:00:51,406 --> 00:00:55,206
is a very important work. 
So, here I'm actually showing the the 

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00:00:55,206 --> 00:00:58,640
title of the original paper by Leon 
Cooper. 

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00:00:58,640 --> 00:01:04,533
So and this work of Cooper eventually has 
progressed, has developed into a much 

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00:01:04,533 --> 00:01:09,503
more sophisticated theory, which is the 
Bardeen-Cooper-Schrieffer theory of 

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superconductivity, also called the BCS 
theory. 

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So, and this BCS theory has been the 
cornerstone of the theory of 

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00:01:18,914 --> 00:01:25,316
superconductivity for many, many years. 
And frankly, there is nothing better on 

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the market in some sense. 
So, this BCS theory describes very well 

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00:01:30,768 --> 00:01:36,228
most conventional superconductors. 
And it provides some understanding also, 

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00:01:36,228 --> 00:01:39,900
in the physics of unconventional 
superconductors. 

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00:01:39,900 --> 00:01:43,695
Although they're sensuously a high 
temperatures super conductors for example 

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00:01:43,695 --> 00:01:47,30
although their understanding is not 
complete. 

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00:01:47,30 --> 00:01:51,432
now as I well I shown many times already 
excitations for various Nobel prizes and 

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00:01:51,432 --> 00:01:55,772
and that just caused briefly a number of 
Nobel prize winning works and they should 

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mid, admit that. 
In most of these cases I had to sort of 

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simplify things enormously when I was 
providing explanations, sort of dumb it 

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00:02:05,66 --> 00:02:09,260
down to some degree. 
So here, well I'm not going to discuss 

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the BCS-theory, this is a very 
complicated theory, but the paper of 

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Cooper is actually very, very simple. 
So, the original paper which started it 

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all is very simple. 
And we will be able to understand 

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00:02:20,410 --> 00:02:23,940
essentially its main message and the 
derivation. 

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Now but before going into this derivation 
let me discuss the origin of this 

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attractive interaction. 
So I basically, w,hat I, what I want to 

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00:02:32,863 --> 00:02:37,259
solve again is a problem of electrons 
interacting via an attractive potential. 

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00:02:37,259 --> 00:02:41,600
But where is it exactly coming from? 
So this is actually very complicated and 

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00:02:41,600 --> 00:02:44,650
intriguing question and well, it 
sometimes the mystery of let's say high 

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temperature of super conductivity is in 
that, we don't really know where it is 

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00:02:47,900 --> 00:02:52,920
sort glue this attractive interaction 
might be coming from. 

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00:02:52,920 --> 00:02:58,766
So the origin of electron interaction and 
conventional super conductors is also far 

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00:02:58,766 --> 00:03:03,750
from obvious actually. 
So, but there was a breakthrough paper 

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00:03:03,750 --> 00:03:08,761
back in the beginning of the 50s. 
so I'm showing you here the title of this 

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00:03:08,761 --> 00:03:13,420
paper, Superconductivity in Iso, of 
Isotopes of Mercury. 

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00:03:13,420 --> 00:03:17,11
And to appreciate the importance of this 
paper, let me just remind you of the 

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00:03:17,11 --> 00:03:22,526
basic picture of, what a metal is. 
So, well, if you have a metallic system, 

46
00:03:22,526 --> 00:03:27,82
well, assorted system, so the reason it's 
assorted is because, the ions form a 

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00:03:27,82 --> 00:03:31,879
crystal lattice. 
So they are positioned in space in a 

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00:03:31,879 --> 00:03:35,988
regular fashion. 
So I'm just drawing here for the sake of 

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00:03:35,988 --> 00:03:40,132
simplicity, as a square a lot as 2D but 
in relatives, it could be more 

50
00:03:40,132 --> 00:03:45,805
complicated. 
Three crystal lattice And, you should 

51
00:03:45,805 --> 00:03:52,196
think about having positive ions sitting 
here in these slides, and these line are 

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00:03:52,196 --> 00:03:56,952
slides. 
And these lattice is sort of elastic, 

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00:03:56,952 --> 00:04:01,488
well it's a recent object but it can have 
a oscillations, waves running through it, 

54
00:04:01,488 --> 00:04:06,24
and we're going to discuss a little bit 
in the few, in a few weeks, and so these 

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00:04:06,24 --> 00:04:11,970
oscillations of the lattice are called 
phonons. 

56
00:04:11,970 --> 00:04:15,890
Now electrons in the metal are moving 
moving around, they're free to move 

57
00:04:15,890 --> 00:04:21,150
around, but they move around in the on 
the background of this lattice. 

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00:04:21,150 --> 00:04:24,490
So this red guys here are electrons. 
Okay? 

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00:04:24,490 --> 00:04:29,885
So this is pretty much what, well it's 
very [UNKNOWN] model, simplified, over 

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00:04:29,885 --> 00:04:36,814
simplified model of, metallic soil. 
Now, so this paper, what this paper has 

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00:04:36,814 --> 00:04:41,106
achieved is that it looked at different 
isotopes of mercury which is a 

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00:04:41,106 --> 00:04:46,644
superconductor. 
And let me remind you that the isotopes 

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00:04:46,644 --> 00:04:51,90
are essentially different versions of the 
same chemical elements. 

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00:04:51,90 --> 00:04:56,112
and basically everything is the same for 
different isotopes apart from the number 

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00:04:56,112 --> 00:05:01,608
of neutrons in each ion sitting on the 
lattice size, but basically. 

66
00:05:01,608 --> 00:05:05,204
So different isotopes means that 
everything is the same, but the only 

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00:05:05,204 --> 00:05:09,710
difference is the mass of these objects 
on the lattice size. 

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00:05:09,710 --> 00:05:13,652
Which well now really shouldn't affect 
too much superconductivity because 

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00:05:13,652 --> 00:05:17,432
clearly superconductivity's coming from 
whatever electron, electrons are doing 

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00:05:17,432 --> 00:05:21,596
and it shouldn't have much to do with the 
lattice. 

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00:05:21,596 --> 00:05:23,714
Right? 
So because these guys are actually, well 

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00:05:23,714 --> 00:05:26,990
they can oscillate a little bit near 
their equilibrium positions, but they 

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00:05:26,990 --> 00:05:31,760
cannot conduct electricity. 
So as it turns out, and this is really 

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the main message of the paper, that the 
transition temperature, in the 

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00:05:35,595 --> 00:05:39,666
superconductor, the temperature at which 
the resistivity drops exactly to zero, 

76
00:05:39,666 --> 00:05:45,790
depended very strongly on the mass of 
these guys. 

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00:05:45,790 --> 00:05:52,80
So and the behavior the ions the lower 
was the transition temperatures. 

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00:05:52,80 --> 00:05:56,234
So here maybe it is hard to see so there 
are a few points so this has average mass 

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00:05:56,234 --> 00:06:00,245
number and this has transition 
temperature. 

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00:06:00,245 --> 00:06:05,105
So so this is basically let me write a tc 
and this is the mass of this ions on 

81
00:06:05,105 --> 00:06:10,134
lattice size. 
Okay and so this was a very clear-cut 

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00:06:10,134 --> 00:06:15,237
trend and it was a smoking gun of that 
superconductivity had something to do 

83
00:06:15,237 --> 00:06:22,720
With interactions between the electrons, 
and decrease the lattice. 

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00:06:22,720 --> 00:06:27,964
So a little later, people realized that 
what actually happens is that this these 

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00:06:27,964 --> 00:06:32,932
electrons, moving around, they whenever 
the electron passes through a region in a 

86
00:06:32,932 --> 00:06:39,231
lattice, essentially because electron's 
negatively charged. 

87
00:06:39,231 --> 00:06:43,787
And the ions sitting on lattice size are 
positively charged, so this electron 

88
00:06:43,787 --> 00:06:49,580
polarizes the lattice, okay, so locally. 
And it takes some time for the lattice 

89
00:06:49,580 --> 00:06:53,284
sort of to relax back. 
And then if a second electron comes in, 

90
00:06:53,284 --> 00:06:56,612
so, let's say I have here now this guy 
goes away, and there's a second electron 

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00:06:56,612 --> 00:07:02,343
which comes in into the same, region. 
So, this, electron, this second electron 

92
00:07:02,343 --> 00:07:06,843
is attracted in some sense to, to this 
region and, this, results in an effective 

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00:07:06,843 --> 00:07:13,60
correlation, effective, phonon-mediated 
attraction between the electrons. 

94
00:07:13,60 --> 00:07:15,547
It's a very tricky business. 
So, I, if you don't understand it, well, 

95
00:07:15,547 --> 00:07:17,925
don't be surprised. 
I don't understand it either. 

96
00:07:17,925 --> 00:07:21,509
Attraction but that's how it works so, 
we'll have to you know just accept this 

97
00:07:21,509 --> 00:07:24,594
fact. 
So that what happens is that electrons in 

98
00:07:24,594 --> 00:07:28,626
some sense they exchange waves elastic 
waves which are called phonons and this 

99
00:07:28,626 --> 00:07:33,620
leads to effective attraction. 
Well, and by the way for the model for 

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00:07:33,620 --> 00:07:37,841
the actual solution, I'm going to present 
the origin of the attraction does matter 

101
00:07:37,841 --> 00:07:41,558
that much it will be just some 
attraction, some constant minus v not 

102
00:07:41,558 --> 00:07:47,469
but, you know, it's good to know the 
physics behind it. 

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00:07:47,469 --> 00:07:51,757
For the actual compilation we'll need a 
specific mathematical model of this 

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00:07:51,757 --> 00:07:56,270
electron, electron attraction. 
And the true attraction the true 

105
00:07:56,270 --> 00:07:59,130
interaction is actually quite 
complicated. 

106
00:07:59,130 --> 00:08:02,784
But here I will present what I call a 
spherical cow model of the phonon 

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00:08:02,784 --> 00:08:08,728
mediated attraction between electrons. 
which I should say actually is used 

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00:08:08,728 --> 00:08:12,910
commonly even in research papers. 
So it works perfectly well. 

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00:08:12,910 --> 00:08:17,509
And even though we know how to write the 
true model which would involve all the 

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00:08:17,509 --> 00:08:22,345
complications of the theory. 
So the results, the outcomes, of the 

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00:08:22,345 --> 00:08:25,810
simplified model and the I'm not going to 
give a little more, or pretty close to 

112
00:08:25,810 --> 00:08:31,40
each other, so there is really no reason 
for us to complicate things. 

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00:08:31,40 --> 00:08:35,371
In any case, so what we were talking 
about is that again, electrons moving 

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00:08:35,371 --> 00:08:39,631
around in a presence of a crystal 
lattice, they exchange, waves drawing 

115
00:08:39,631 --> 00:08:46,205
through the lattice are these phonons. 
And so this diagram is an example of a 

116
00:08:46,205 --> 00:08:50,950
fine metallic like diagram which shows 
this kind of a change. 

117
00:08:50,950 --> 00:08:55,795
And in any process like this we must 
satisfy basic conservation laws 

118
00:08:55,795 --> 00:09:03,170
particularly when must ensure that both 
energy and momentum are conserved. 

119
00:09:03,170 --> 00:09:08,474
So and therefore what's important here in 
understanding the structure of this 

120
00:09:08,474 --> 00:09:13,890
interaction is the typical energies 
involved in such processes. 

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00:09:13,890 --> 00:09:17,90
So what we know, what we've already 
discussed is the the typical energy of 

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00:09:17,90 --> 00:09:22,500
the electrons in the in the middle. 
So and this typical energy, I denoted as 

123
00:09:22,500 --> 00:09:26,855
E sub F, the Fermi energy divided by the 
Boseman constant, sort of to convert into 

124
00:09:26,855 --> 00:09:31,730
a more, familiar temperature units so the 
corresponding typical sort of temperature 

125
00:09:31,730 --> 00:09:37,560
of electrons is going to be about 10,000 
Kelvin. 

126
00:09:37,560 --> 00:09:40,570
So this guys which are actually the main 
players. 

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00:09:40,570 --> 00:09:45,730
Of the theory have the energy, which you 
shall see with this temperature scale. 

128
00:09:45,730 --> 00:09:51,650
Now it turns out that the phonons, it's 
not obvious from the previous discussion. 

129
00:09:51,650 --> 00:09:55,682
It's not something we can get at, I'm 
just giving you an experimental fact, is 

130
00:09:55,682 --> 00:09:59,273
that if the typical energy of the 
phonons, which I will call s h times I 

131
00:09:59,273 --> 00:10:05,940
mean divide, so called divide frequency 
divided by the Boseman constant. 

132
00:10:05,940 --> 00:10:10,100
So when convert it into temperatures, 
it's about 400 kelvin. 

133
00:10:10,100 --> 00:10:13,14
A few hundred kelvin, so, which is two 
orders of magnitude smaller than the 

134
00:10:13,14 --> 00:10:16,804
energy of the electron. 
So what we should think about is that, 

135
00:10:16,804 --> 00:10:21,156
this phonon actually being exchanged by 
the electrons have energy which is much, 

136
00:10:21,156 --> 00:10:25,337
much more than the electron energy 
itself. 

137
00:10:25,337 --> 00:10:31,177
And, this, puts certain constrains on the 
possible, momentum and energies of the 

138
00:10:31,177 --> 00:10:36,50
electrons that may experience sort of a 
process. 

139
00:10:36,50 --> 00:10:40,610
And the simplest, sort of, version of the 
interaction which takes this into account 

140
00:10:40,610 --> 00:10:45,592
is, presented here. 
So this is an equation for an 

141
00:10:45,592 --> 00:10:50,272
interaction, momentum independent 
interaction between the two electrons V 

142
00:10:50,272 --> 00:10:55,24
of p and what it tells us that the two 
electrons attract each other in this 

143
00:10:55,24 --> 00:10:59,704
language if they are located in the 
narrow shell near the Fermi surface and 

144
00:10:59,704 --> 00:11:08,490
the width of the shell is of the order of 
this phonon energy. 

145
00:11:08,490 --> 00:11:11,955
So basically if, two electrons can 
exchange phonons, they do so and this 

146
00:11:11,955 --> 00:11:15,365
results in the attraction which is 
manifested here through this negative 

147
00:11:15,365 --> 00:11:20,190
coefficient. 
And V naught is some constant. 

148
00:11:20,190 --> 00:11:25,230
And if two electrons are located well, 
beyond this narrow region So then they 

149
00:11:25,230 --> 00:11:29,630
don't have a mechanism to attract each 
other. 

150
00:11:29,630 --> 00:11:35,570
And their interaction, therefore, is 0. 
So if we look just at the upper part. 

151
00:11:35,570 --> 00:11:40,628
So v of p is equal to minus v, 0. 
So this would correspond to, essentially, 

152
00:11:40,628 --> 00:11:44,736
a local attraction real speed. 
So this is something that we actually 

153
00:11:44,736 --> 00:11:48,262
saw. 
In, lecture number five for the delta 

154
00:11:48,262 --> 00:11:51,800
potential. 
So this is the kind of problem we, 

155
00:11:51,800 --> 00:11:56,806
discussed already. 
And, but, however, then, we were talking 

156
00:11:56,806 --> 00:12:01,910
about the, one particle in a, in an 
quantum well. 

157
00:12:01,910 --> 00:12:06,667
So now we're talking about two particles 
two excitations interacting with each 

158
00:12:06,667 --> 00:12:11,559
other by this potential. 
But per, well put the results of the 

159
00:12:11,559 --> 00:12:16,743
previous segment in this lecture we know 
that the two particle problem and quantum 

160
00:12:16,743 --> 00:12:21,711
mechanics is to a large degree equivalent 
to a single particle quantumic angle 

161
00:12:21,711 --> 00:12:25,959
problems and as we discussed in the 
previous video the only difference 

162
00:12:25,959 --> 00:12:33,673
between the. 
single particle problem in potential v of 

163
00:12:33,673 --> 00:12:38,710
r and 2 particle problem of 2 particles 
interacting by the same potential is that 

164
00:12:38,710 --> 00:12:43,333
in the lecture we will get the reduced 
mass instead of the mass of eac, of each 

165
00:12:43,333 --> 00:12:50,284
individual particle. 
And in the case of two identical 

166
00:12:50,284 --> 00:12:53,680
electrons the reduced mass is equal to m 
r 2. 

167
00:12:53,680 --> 00:12:56,530
So we, we have this simply this 
Schrodinger equation. 

168
00:12:56,530 --> 00:13:00,235
And here I write it first in real space 
sort of but keeping in mind that there 

169
00:13:00,235 --> 00:13:04,460
are in fact additional constraints on the 
interaction. 

170
00:13:04,460 --> 00:13:08,816
So if we do if we follow the same route 
that we did in lecture number five and do 

171
00:13:08,816 --> 00:13:14,666
Fourier transform. 
So, we can write this equation in this 

172
00:13:14,666 --> 00:13:20,630
form, so delta of r emptying on psi of r 
picks up psi of of 0. 

173
00:13:20,630 --> 00:13:24,310
And so here I'm going to have this 
integral over all momentum. 

174
00:13:24,310 --> 00:13:28,730
But basically a way to introduce 
constraints on the potential which we 

175
00:13:28,730 --> 00:13:33,82
just discussed would be to limit the 
integration or momentum here by only 

176
00:13:33,82 --> 00:13:37,910
momenta that appear in the vicinity of 
the Fermi surface, you know, so that the 

177
00:13:37,910 --> 00:13:46,203
possibility of phonon exchange exists. 
And so this equation essentially, these 2 

178
00:13:46,203 --> 00:13:50,490
equations with the appropriate sort of 
caveats. 

179
00:13:50,490 --> 00:13:54,434
About where this reaction is possible is 
exactly the Cooper pairing problem, and 

180
00:13:54,434 --> 00:13:58,784
as you can see it's essentially identical 
mathematically to the kinds of problems 

181
00:13:58,784 --> 00:14:05,10
we saw in lecture number five in the 
single particle of quantum mechanics. 

182
00:14:05,10 --> 00:14:09,630
And so, well we can we can follow the 
same route but at at this stage we may be 

183
00:14:09,630 --> 00:14:14,506
a little bit surprised by this 
resemblance. 

184
00:14:14,506 --> 00:14:18,598
Because, I mentioned that this, 
eventually the result of this calculation 

185
00:14:18,598 --> 00:14:23,905
is going to be the appearance of a bound 
state between the two electrons. 

186
00:14:23,905 --> 00:14:28,461
But, as we discussed, weak attraction in, 
three dimensions, and this is a 

187
00:14:28,461 --> 00:14:33,330
3-dimensional problem, does not result in 
a bound state. 

188
00:14:33,330 --> 00:14:36,792
So delta function potentially 3D does not 
have a bound state. 

189
00:14:36,792 --> 00:14:41,622
Uh,however, an interesting thing that 
happens here is that because electrons 

190
00:14:41,622 --> 00:14:46,592
really play a role in, in this, pairing 
and this interaction, with for-nodes, 

191
00:14:46,592 --> 00:14:52,190
they exist in the vicinity of this firmer 
surface. 

192
00:14:52,190 --> 00:14:56,192
And this surface is two dimensional. 
This, gives rise, in a sense, to 

193
00:14:56,192 --> 00:15:01,244
reduction of dimensionality. 
Although, in real space, we started with 

194
00:15:01,244 --> 00:15:06,488
a three dimensional, system, so this 
effectively what you are dealing with, 

195
00:15:06,488 --> 00:15:13,72
with here has used dimension. 
And this gives rise to the appearance of 

196
00:15:13,72 --> 00:15:19,526
a bond state in a very unexpected way. 
So, to see this we essentially have to 

197
00:15:19,526 --> 00:15:27,382
repeat exactly the same steps as we did 
in parts 3 and 4 of lecture number 5. 

198
00:15:27,382 --> 00:15:31,870
So, so the only difference here is due to 
the fact that this energy in the left 

199
00:15:31,870 --> 00:15:38,570
hand, in the right-hand side, if we want 
to find, really consists of two parts. 

200
00:15:38,570 --> 00:15:42,350
So this is the energy of the electrons 
that already have a finite energy at the 

201
00:15:42,350 --> 00:15:46,592
at the Fermi surface. 
So remember is that we're talking here 

202
00:15:46,592 --> 00:15:51,80
about these excitations that have the 
energy of two E-Fermi, and then there is 

203
00:15:51,80 --> 00:15:56,960
an energy due to the interaction which we 
want to negative. 

204
00:15:56,960 --> 00:16:00,672
So if this guy delta is negative, it 
means that we can have former bonds 

205
00:16:00,672 --> 00:16:05,30
stayed, and by doing so lowering, lower 
the energy. 

206
00:16:05,30 --> 00:16:09,400
So and well this fact actually makes all 
the difference. 

207
00:16:09,400 --> 00:16:13,365
Actually this is how mathematically the 
fact that we're dealing with this 

208
00:16:13,365 --> 00:16:19,775
manifest itself in this equation. 
Since the remaining calculation follows 

209
00:16:19,775 --> 00:16:24,350
almost 1 to 1, that in lecture number 5, 
and I also present this particular 

210
00:16:24,350 --> 00:16:28,775
calculation, all the details in 
additional materials, so you can read 

211
00:16:28,775 --> 00:16:34,122
through this. 
So I'm not going to repeat this again in 

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this video. 
So what I'm going to do, I'm going to 

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just present the final result for this 
Our key parameter delta which again is 

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the energy of the bounced state of two 
electrons that form sort of a large 

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molecule, if you want, which is called 
Gutterberg here. 

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So and this delta is is going to be of 
the water of minus h of energy so this is 

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phonon energy, typical phonon energy that 
we discussed in the previous slide. 

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But the key thing here is that there is 
multiplied by an. 

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Exponential of minus one, some constant, 
I'll call it n naught, and define it in a 

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second, times v naught. 
So where n naught is equal to m, p fermi, 

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so this is this threshold momentum, 
divided by 4 pi squared, hq. 

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So this is just constant, but what I want 
to emphasize, well, first of all, there 

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is a solution, which is great. 
So the electrons indeed,can find a way to 

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lower their energy by forming these 
[UNKNOWN] that eventually form the 

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super-conductor. 
but what is not so great is that these 

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small interaction energy appears in the 
exponential in, minus 1 over d naught. 

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So if you notice, small then, well the, 
energy of the bound state, so 

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called,[UNKNOWN], is exponentially small 
and this is exactly what happens. 

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And those of you followed, all segments 
in lecture number five can recognize. 

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This result is a result that we have 
seen, actually, in the context of 

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two-dimensional, single particle problem. 
And this reflects this reduction in 

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dimensionality that I mentioned before. 
So, the last two things I'm going to 

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mention in the end is. 
First of all, this result. 

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For delta is a function of not is a very 
unusual function which we've already seen 

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but, this function is special because it 
doesn't have a Taylor expansion. 

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So there is no way one can approach this 
result by doing so called perturbation 

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theory. 
And this may be one of the reasons why it 

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took so long for people to figure out the 
heat of super conductivity, because there 

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was no way to approach, it sort of in a 
conservative way. 

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And, the last thing I am going to 
mention, is that well, if we did not have 

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this exponential, if we were to image 
that this delta was the order of this 

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phonon energy. 
This would have actually implied that we 

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can get super conductivity at very high 
temperatures up to room temperatures. 

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So, this would have been great we would 
have the ability to transport electricity 

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with no losses. 
So, this is really the grand challenge in 

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the field of how to go beyond this 
coupling this so called weak coupling. 

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Bearing model, so how to first of all 
describe this situation where the 

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interaction is so strong and how to get 
rid of this exponentially this is a sort 

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of practical problem that there's no 
solution at the moment. 

